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Deactivation of Radioactive Waste by Transmutation Reduces Danger Period from Millions of Years to 300 Years

In order to decrease the isolation time for radioactive waste, first of all, the actinides - elements whose nuclei are heavier than uranium (i.e. curium, actinium) - must be removed from the waste by processing (transmutation) into short-lived nuclei. “The core concept of transmutation – which was formulated as early as mid 20th century – consists of irradiating the actinides by fast neutrons. The highly stimulated nuclei that are generated this way suffer a fission, which leads to relatively short-lived nuclei, which in turn rapidly disintegrate into stable isotopes. Then, they cease to be radioactive,” explains Professor Helmut Leeb from the Atomic Institute of the Austrian Universities.

Thus, the required radioactive waste isolation time of several millions years could be decreased to 300 and up to 500 years. The technological progress made in the last decades has made the transmutation possible at the industrial level.

An efficient transmutation of radioactive waste requires the development of new facilities. In addition to specially designed fast reactors, the Accelerator-Driven Systems (ADS) present a new potential concept. This is an undercritical reactor, which cannot sustain any chain reaction. The neutrons necessary for stationary operations are supplied by a proton accelerator with a spallation target located in the reactor core. “During the spallation, the atomic nuclei of the target (mainly lead) are broken with high-energy protons, while a large number of neutrons are normally released, neutrons which are necessary for the stationary operation of the reactor. If the accelerator is turned off, the chain reaction ceases,” added Leeb. Worldwide studies are based on the assumption that at least two decades will be necessary to transfer this concept to the industrial level, a concept which is fully understood at the scientific level.

An essential prerequisite for this development is a thorough knowledge of the neutrons’ interaction and reactions with other materials as available to date. Therefore, in the year 2000, the n_Tof facility became operative at CERN (Genf), which is a unique facility in the world, suitable especially for measuring the reactions of radioactive materials when bombarded with neutrons. Between 2002 and 2005, a large number of radiative captures and fission reactions, previously insufficiently known, were measured as part of an EU project, in which nuclear physicists from TU Vienna were considerably involved. After the conditional pause occasioned by the construction of the Large Hadron Collider at CERN, now at the end of September 2008, the consortium will start the operations at the upgraded n_TOF facility with a new target. The first series of experiments are neutron radiative captures on iron and nickel, which are analyzed by Viennese nuclear physicists (from TU Vienna and the University of Vienna). In addition to accurate reaction data for transmutation facilities, the results are also of interest for Astrophysics.

An alternative nuclear fuel, which leads to a reduced incidence of radioactive waste, is the “thorium-uranium cycle.” Leeb: “Thorium is a potential nuclear fuel, which may be incubated into a light uranium isotope, whose fission generates basically no actinide. Furthermore, thorium can be found approximately five times more often than uranium. However, special reactors must be still developed for this, reactors that would be appropriate for the reaction pattern and for the somewhat harder gamma radiation. India is one of the countries that already host experiments with thorium in reactor cores.

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