Linde Gases Contributes to the Making of Environmentally Friendly Computer Chips

Pioneering the European electronics industry’s efforts for sustainable   manufacturing of semiconductors, Linde Gases, a division of The   Linde Group, has installed Europe’s first CE-marked on-site electronics   grade fluorine (F2) generator at STMicroelectronics’ Crolles 300mm wafer   fabrication plant in France. As part of STMicroelectronics’ initiative   to lower the environmental impact of producing semiconductors, high-pressure   cylinder F2 has been replaced by two new Linde Generation-F® on-site fluorine   generators – providing a low pressure, fully redundant supply of high   purity F2 and eliminating the need to transport to and keep cylinders on site.

The Linde fluorine generators and ancillary equipment combine proven technology   with intrinsically safe design to provide STMicroelectronics an on-demand, safe   and highly reliable source of pure F2 for Chemical Vapour Deposition (CVD) chamber   cleaning. One cylinder of hydrogen fluoride (used as the source material for   the on-site generator) provides the same amount of F2 to the fab as 100 high   pressure F2 cylinders – significantly reducing maintenance workload, while   the very low system pressure provides much greater safety for all STMicroelectronics   engineers.

“As operators of thermal CVD furnaces look to optimize costs and minimize   risk through stricter safety requirements, Linde is seeing a quicker pace of   adoption for on-site generated fluorine,” said Greg Shuttleworth, Semiconductor   Product Manager for Linde Gases Division. “We are also seeing increasing   interest in using F2 as an alternative to NF3 for the cleaning of Plasma-Enhanced   CVD chambers due to concerns over the very high global warming potential of   NF3 and imminent legislation that could restrict its use.”

“The installation of Europe’s first on-site fluorine generators   at our Crolles wafer fabrication plant is testament to STMicroelectronics’   commitment to increasing safety and improving our eco-footprint,” said   David Ferrand, Director of Facilities at the Crolles 200 and Crolles 300 fabs.   “We have directly reduced our carbon footprint at Crolles 300mm by eliminating   cylinder deliveries. We are excited by the potential for even greater environmental   efficiency by using the generation capacity in other cleaning applications.”

Previously, every cylinder change was an opportunity for contamination of the   system, but now the STMicroelectronics Crolles 300mm facility has much greater   reliability of gas box components by eliminating these frequent changes. There   is also less hazardous waste as there is no need to purge cylinders to ensure   they are completely empty before changing, increasing savings and reducing the   load on STMicroelectronics’ abatement systems.

The Linde Generation-F® on-site fluorine generator has been through extensive   third-party safety evaluations and can now add the CE Mark to the SEMI S2 certificate   among its list of national and industry recognised safety standards. In addition   to the generators themselves, Linde’s ancillary buffer and abatement systems,   which safely deliver variable amounts of fluorine, have also been CE-marked   and SEMI S2 certified. Including those at STMicroelectronics, Linde has supplied   and operates nearly 30 Generation-F® systems worldwide to meet the semiconductor,   display and photovoltaic industries’ chamber cleaning needs.

STMicroelectronics' programs to reduce the use of energy, water and chemicals   at all sites are the foundation of its longstanding eco-efficiency approach   to environmental stewardship. STMicroelectronics considers the management of   the chemicals it uses, along with climate change, as the most important environmental   issues, and has been reducing chemical consumption by more than five percent   a year, on average, since 1998.

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